heinz-siedentop

Analysis and Mathematical Physics

Ludwig-Maximilians-Universität München

Mathematischal Institute

Theresienstr. 39

80333 Munich

Tel. +49 89 2180 4404

h.s[at]lmu.de

Group Webpage

Description

Research focus: mathematical physics, atomic and quantum many-body physics

Our group is devoted to mathematical analysis and mathematical physics. See more information in our publication list .

Publications

A Statistical Theory of Heavy Atoms: Asymptotic Behavior of the Energy and Stability of Matter

H. Siedentop

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We give the asymptotic behavior of the ground state energy of Engel's and Dreizler's relativistic Thomas-Fermi-Weizsäcker-Dirac functional for heavy atoms for fixed ratio of the atomic number and the velocity of light. Using a variation of the lower bound, we show stability of matter.

arXiv:2101.06539

The Strong Scott Conjecture: the Density of Heavy Atoms Close to the Nucleus

H. Siedentop

in Book: Spectral Theory and Mathematical Physics 257-272 (2020).

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We review what is known about the atomic density close to the nucleus of heavy atoms.

DOI: 10.1007/978-3-030-55556-6_14

A statistical theory of heavy atoms: energy and excess charge

H. Chen, R.L. Frank, H. Siedentop

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The purpose of this note is to give an elementary derivation of a lower bound on the relativistic Thomas-Fermi-Weizsäcker-Dirac functional of Thomas-Fermi type and to apply it to get an upper bound on the excess charge of this model.

arXiv:2010.12074

Relativistic Scott conjecture: a short proof

R.L. Frank, K. Merz, H. Siedentop

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We consider heavy neutral atoms of atomic number Z modeled with kinetic energy (c^2p^2+c^4)^1/2−c^2 used already by Chandrasekhar. We study the behavior of the one-particle ground state density on the length scale Z−1 in the limit Z,c→∞ keeping Z/c fixed. We give a short proof of a recent result by the authors and Barry Simon showing the convergence of the density to the relativistic hydrogenic density on this scale.

arXiv:2009.02474

On the excess charge of a relativistic statistical model of molecules with an inhomogeneity correction

H. Chen, H. Siedentop

Journal of Physics A 53, 395201 (2020).

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We show that the molecular relativistic Thomas–Fermi–Weizsäcker functional consisting of atoms of atomic numbers Z1, ..., Zk has a minimizer, if the particle number N is constrained to a number less or equal to the total nuclear charge Z := Z1 + ⋯ + ZK. Moreover, there is no minimizer, if the particle number exceeds 2.56Z. This gives lower and upper bounds on the maximal ionization of heavy atoms.

DOI: 10.1088/1751-8121/aba4d3

Proof of the Strong Scott Conjecture for Heavy Atoms: the Furry Picture

K. Merz, H. Siedentop

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We prove the convergence of the density on the scale Z−1 to the density of the Bohr atom (with infinitely many electrons) (strong Scott conjecture) for a model that is known to describe heavy atoms accurately.

arXiv:2007.03895

Proof of the strong Scott conjecture for Chandrasekhar atoms

R.L. Frank, K. Merz, H. Siedentop, B. Simon

Pure and Applied Functional Analysis 5 (6), 1319 - 1356 (2020).

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We consider a large neutral atom of atomic number Z, taking relativistic effects into account by assuming the dispersion relation √(c^2p^2+c^4). We study the behavior of the one-particle ground state density on the length scale Z−1 in the limit Z,c→∞ keeping Z/c fixed and find that the spherically averaged density as well as all individual angular momentum densities separately converge to the relativistic hydrogenic ones. This proves the generalization of the strong Scott conjecture for relativistic atoms and shows, in particular, that relativistic effects occur close to the nucleus. Along the way we prove upper bounds on the relativistic hydrogenic density.

yokohamapublishers.jp/online2/oppafa/vol5/p1319

Equivalence of Sobolev Norms Involving Generalized Hardy Operators

R.L. Frank, K. Merz, H. Siedentop

International Mathematics Research Notices 2021, 2284-2303 (2019).

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We consider the fractional Schrödinger operator with Hardy potential and critical or subcritical coupling constant. This operator generates a natural scale of homogeneous Sobolev spaces, which we compare with the ordinary homogeneous Sobolev spaces. As a byproduct, we obtain generalized and reversed Hardy inequalities for this operator. Our results extend those obtained recently for ordinary (non-fractional) Schrödinger operators and have an important application in the treatment of large relativistic atoms.

DOI: 10.1093/imrn/rnz135

The Atomic Density on the Thomas-Fermi Length Scale for the Chandrasekhar Hamiltonian

K. Merz, H. Siedentop

Reports on Mathematical Physics 83, 387-391 (2019).

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We consider a large neutral atom of atomic number Z, modelled by a pseudo-relativistic Hamiltonian of Chandrasekhar. We study its suitably rescaled one-particle ground state density on the Thomas–Fermi length scale Z−1/3. Using an observation by Fefferman and Seco, we find that the density on this scale converges to the minimizer of the Thomas–Fermi functional of hydrogen as Z → ∞ when Z/c is fixed to a value not exceeding 2/π. This shows that the electron density on the Thomas–Fermi length scale does not exhibit any relativistic effects.

DOI: 10.1016/S0034-4877(19)30057-6

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